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2,4-HEXADIEN-1-OL

PROHIBITION
CAS
111-28-4
EC
—
Material type
other
Canonical source
document derived
Formulation

Usage guidance

Suggested min
—
Suggested max
—
Cost
—
Stock
—
Compatibility tags
green-accordfruityfloral
How it behaves

Olfactory profile

Family
floral
Note tendency
Middle
Descriptors
floralgreensweetoilygrassy

A green, slightly fatty alcohol with a fresh cut-stem character and a mild waxy-oily undertone. Softer and more vegetal than hexenol, with a subtle herbaceous nuance rather than sharpness.AI · claude-opus-4-7

Intensity
5 / 10
Tenacity
4 / 10
Volatility
6 / 10
Members

The rest of this material

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chemicals · No. 1577

Arctander monograph

Perfume and Flavor Chemicals, page 651.

TOP
floralgreensweetoilygrassy
MW
—
BP
177°C
MP
31°C
Sp.Gr.
—
Refractive n
—
Rotation
—
Appearance

Colorless or white needle-like crystals.

Solubility

Almost insoluble in water, soluble in alcohol and oils.

Odor

Sweet-oily, green odor, somewhat grassy-weedy, but quite refreshing and moderately tenacious. The alcohol oxidizes very easily in air and this process affects the odor considerably to the disadvantage of the pleasantness of this alcohol.

Uses in perfumery

This conjugated diene alcohol is occasionally used in perfume compositions as part of a “green note”’, mostly for top note effects in Muguet or Lily, but also in various non-floral types.

Production

1) by Ponndorf reduction (with Aluminum iso-propoxide in iso-Propanol solution) of the corresponding aldehyde, Hexadienal. 2) the alcohol can also be obtained by reduction of the Ethyl ester of the acid, Sorbic acid, which is prepared from Croton aldehyde by MaIonic acid condensation.

Identity
Aliases · 8
17102-64-61-Hydroxy-2,4-hexadiene2,4-Hexadien-1-olHexa-2,4-dien-1-olHexadienolHexadienol (commercial name)Sorbic alcoholSorbyl alcohol
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).