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METHYL CROTONATE

PROHIBITION
CAS
623-43-8
EC
—
Material type
other
Canonical source
document derived
Formulation

Usage guidance

Suggested min
—
Suggested max
—
Cost
—
Stock
—
Compatibility tags
fruity-accordgreen-accord
How it behaves

Olfactory profile

Family
green
Note tendency
Top
Descriptors
sharpgreenfruity

A sharp, pungent ester with a green fruity character reminiscent of unripe apple and cabbage-like sulfury facets. Volatile and diffusive, with a slightly acrid edge typical of small unsaturated methyl esters.AI · claude-opus-4-7

Intensity
7 / 10
Tenacity
2 / 10
Volatility
9 / 10
Members

The rest of this material

Composition, IFRA restriction figures, allergen concentrations and where this material is bought are part of Perfume Foundry’s curated library and need an account. Create one or sign in.

chemicals · No. 1968

Arctander monograph

Perfume and Flavor Chemicals, page 841.

TOPtenacity · lowpower · diffusive
sharpgreenfruity
MW
100.12
BP
121°C
MP
—
Sp.Gr.
0.98
Refractive n
—
Rotation
—
Appearance

Colorless mobile liquid.

Solubility

Practically insoluble in water, miscible with alcohol and oils, soluble in propylene glycol.

Odor

Powerful and diffusive, sharp and green-fruity odor of poor tenacity.

Flavor

Concentrations below 50 ppm have a sweet, fruity, yet slightly pungent taste.

Uses in perfumery

This ester has found a little use in perfumery, mostly as part of various fruit notes, Strawberry in particular. Indirectly, it may find its way into a multitude of fragrance types where such topnotes are applicable: Rose, Jasmin, Gardenia, Freesia, etc. It performs very well with Clary Sage and Lavender, to which it gives power and lift, bringing these fragrances right up into the topnote section of the perfume.

Production

Produced by direct esterification of methanol with 2-butenoic acid under azeotropic conditions.

Identity
Aliases · 4
2-Butenoic acid, methyl ester, (E)-Methyl crotonateMethyl-alpha-crotonateMethyl trans-2-butenoate
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).