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NOOTKATONE

SPECIFICATION
CAS
4674-50-4
EC
—
Material type
other
Canonical source
document derived
Formulation

Usage guidance

Suggested min
—
Suggested max
—
Cost
—
Stock
—
Compatibility tags
citrus-colognefruitychyprefreshhesperidic
How it behaves

Olfactory profile

Family
fruity
Note tendency
Middle
Descriptors
fruitysweetcitrusy

The signature aroma chemical of grapefruit — a juicy, tart citrus with a distinctive bitter-woody undertone. Unlike bright citrus terpenes it has a fuller, more rounded body and a slightly sulfurous, peel-like edge that gives grapefruit accords their characteristic depth and persistence.AI · claude-opus-4-7

Intensity
7 / 10
Tenacity
5 / 10
Volatility
6 / 10
Members

The rest of this material

Composition, IFRA restriction figures, allergen concentrations and where this material is bought are part of Perfume Foundry’s curated library and need an account. Create one or sign in.

chemicals · No. 2382

Arctander monograph

Perfume and Flavor Chemicals, page 1034.

TOPtenacity · highpower · strongG.R.A.S.
fruitysweetcitrusy
MW
218.34
BP
—
MP
—
Sp.Gr.
—
Refractive n
—
Rotation
—
Appearance

Almost colorless, or pale yellowish oily liquid when pure. Some commercial grades are orange-colored, slightly viscous.

Solubility

Practically insoluble in water, soluble in alcohol and oils.

Odor

The title material has an extremely powerful fruity, sweet and citrusy odor of good tenacity.

Flavor

Nootkatone has a pleasant taste in concentrations lower than 50 ppm, and although preliminary reports indicate that the material has a perceptible flavor down to 1 ppm, the author is inclined to claim that the minimum perceptible for Nootkatone is between 0.1 and 0.2 ppm.

Uses in perfumery

The title ketone could undoubtedly find use in perfume compositions for novel effects in topnote compositions, particularly in combination with Bergamot oil, Bitter Orange oil, Hexenyl esters, Aldehydes, etc.

Uses in flavor

The interesting fact is that the material has a typical Grapefruit peel taste at levels higher than 3 ppm and lower than 50 ppm.

Production

The sesquiterpene Valencene is isolated from Orange juice oil and oxidized with tertiary-Butyl chromate to yield the title ketone.

Identity
Aliases · 13
2(3H)-Naphthalenone, 4,4a,5,6,7,8-hexahydro-4,4a-dimethyl-6-(1-methylethenyl)-,2(3H)-Naphthalenone, 4,4a,5,6,7,8-hexahydro-4,4a-dimethyl-6-(1-methylethenyl)-, (4R,4aS,6R)-4,4a,5,6,7,8-Hexahydro-6-isopropenyl-4,4a-dimethyl-2(3H)-naphthalenone4a,5-Dimethyl-1,2,3,4,4a,5,6,7-octahydro-7-keto-3-isopropenylnaphthalene4betaH,5alpha-Eremorphila-1(10),11-dien-2-one(4R-(4alpha,4a alpha,6beta))-4,4a,5,6,7,8-Hexahydro-4,4a-dimethyl-6-(1-(4R-(4alpha,4a alpha,6beta))-4,4a,5,6,7,8-Hexahydro-4,4a-dimethyl-6-(1-methylvinyl)naphthalen-2(3H)-one(4R,4aS,6R)-5,6-Dimethyl-8-isopropenylbicyclo(4.4.0)dec-1-en-3-onemethylvinyl)naphthalen-2(3H)-oneNootkatone5,6-Dimethyl-8-iso-propenylbicyclo-(4,4,0)-dec-1-en-3-oneNootkatin
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).