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BENZOIN

CAS
—
EC
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Material type
synthetic aroma chemical
Canonical source
arctander

Benzoin is a natural balsamic resin, the hardened exudate collected by wounding the bark of Styrax trees, most commonly Styrax tonkinensis (Siam benzoin) and Styrax benzoin (Sumatra benzoin); several CAS numbers exist because these regional resin sources are chemically and commercially distinct rather than a single defined substance, so no single CAS is truly definitive for "benzoin" as a category. In perfumery the raw resin is rarely used directly — it is typically dissolved and processed into a resinoid (often cut in a solvent such as benzyl benzoate or DPG for workable viscosity) or, less often, an absolute. Siam benzoin tends toward a softer, sweeter, vanilla-like and creamy balsamic character, while Sumatra benzoin leans slightly darker, drier and more smoky-phenolic. Olfactively it reads as warm, sweet, powdery-vanillic and resinous, with honeyed and faintly spicy undertones. It is used almost exclusively as a base-note material, prized as a fixative that slows evaporation and rounds out sharper top and heart notes; typical dosage is low, often well under a few percent of a formula. It anchors oriental, amber, gourmand and incense-type accords, and pairs naturally with vanilla, labdanum, tonka, and other balsamic or resinous materials. Because natural benzoin resinoids contain constituents like benzyl benzoate and cinnamic derivatives, they carry some recognized skin-sensitization potential, so use levels are generally kept conservative and monitored under industry safety guidance rather than left unrestricted. — researched, 2026-09-02.

Formulation

Usage guidance

Suggested min
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Suggested max
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Cost
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Stock
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Compatibility tags
amberorientalgourmandincensefougerechypre
How it behaves

Olfactory profile

Family
sweet
Note tendency
Base
Descriptors
sweet

A thick, sweet balsamic resin with a pronounced vanilla-like warmth and a soft powdery undertone. Rich and syrupy in character, with faint cinnamic and slightly smoky facets that give it a comforting, church-incense feel. Acts as a natural fixative that rounds and sweetens amber and oriental accords.AI · claude-opus-4-7

Intensity
6 / 10
Tenacity
9 / 10
Volatility
2 / 10
Members

The rest of this material

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chemicals · No. 277

Arctander monograph

Perfume and Flavor Chemicals, page 124.

G.R.A.S.FEMA 2132
sweet
MW
—
BP
344°C
MP
137°C
Sp.Gr.
—
Refractive n
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Rotation
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Appearance

White crystals.

Solubility

Slightly soluble in hot water. Slightly soluble in alcohol and oils.

Odor

Very faint, sweet, nondescript odor.

Flavor

Suggested for use (and actually used) in imitation Butter flavors, Butterscotch, Fruit, Liquor, Vanilla, etc. and in imitation Rum flavors.

Uses in flavor

This chemical is used mainly in beverages (at concentrations about 5 ppm), but the actual extension of use is very small.

Production

Produced from Benzaldehyde in alcoholic solution with Sodium cyanide.

Identity
Aliases · 3
BENZOIN2-Hydroxy-2-phenylacetophenonedl-Benzoyl phenylcarbinol
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).