Cis-3-Hexenyl Benzoate (CAS 25152-85-6) is a synthetic aroma chemical commonly used in perfumery for its fresh, green, and fruity character, reminiscent of freshly cut grass and certain fruits. It is often employed in floral and fruity compositions, where it can enhance the overall freshness and add a natural green note. This ingredient typically sits in the top to middle notes of a fragrance formula, contributing to the initial impression and the heart of the scent. In terms of safety and regulatory considerations, it is important for perfumers to be aware of any potential restrictions or guidelines set by organizations such as IFRA, as synthetic aroma chemicals can sometimes be subject to specific usage limits due to safety assessments. While cis-3-Hexenyl Benzoate is not widely recognized as a common allergen, it is always advisable to consult the latest safety data sheets and regulatory documents to ensure compliance and safety in formulations. — AI-generated summary, 2026-09-02.
A soft, natural green-fruity note with a leafy, slightly floral character reminiscent of crushed cis-3-hexenol married to a mild sweet balsamic backdrop from the benzoate. Rounder and more tenacious than leaf alcohol itself, with a subtle pear/apple skin nuance and a clean, slightly powdery drydown.AI · claude-opus-4-7
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Other ingredients whose composition declares this material as a constituent. The percentage shown is the supplier-declared concentration in that parent.
| Ingredient | % | Range |
|---|---|---|
| GARDENIA J. ELLIS | — | 1–5% |
Perfume and Flavor Chemicals, page 666.
Colorless, slightly viscous liquid.
Practically insoluble in water, soluble in alcohol and oils.
Mild, but tenacious, green-herbaceous and woody odor.
The major asset of this ester is its tenacity. As a 'green' material it is much weaker than the esters of the lower aliphatic acids. But the milder odor makes it easier to handle, and the gentle, green-herbaceous effect can be suitably utilized in Fougeres, New Mown Hay compositions, Chypres, etc. It blends very well with Styrax materials and the Phenylethyl alcohol family, with Amyl salicylate and Coumarin, Oakmoss and Ylang-Ylang.
Produced by esterification of cis-3-Hexenol with Benzoic acid (or with Benzoyl chloride).