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CIS-3-HEXENYL FORMATE

CAS
—
EC
—
Material type
synthetic aroma chemical
Canonical source
arctander
Formulation

Usage guidance

Suggested min
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Suggested max
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Cost
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Stock
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Compatibility tags
green-floralfruityfougerecolognemuguettea
How it behaves

Olfactory profile

Family
green
Note tendency
Base
Descriptors
floralgreensweetwaxy

Intensely green and leafy with a sharp, freshly-crushed foliage character — like torn grass and bruised leaves with a slight unripe-fruit facet. More pungent and rougher than cis-3-hexenol, with a faint ethereal/estery lift on top that fades to a clean vegetal green.AI · claude-opus-4-7

Intensity
8 / 10
Tenacity
2 / 10
Volatility
9 / 10
Members

The rest of this material

Composition, IFRA restriction figures, allergen concentrations and where this material is bought are part of Perfume Foundry’s curated library and need an account. Create one or sign in.

chemicals · No. 1620

Arctander monograph

Perfume and Flavor Chemicals, page 670.

drygreenpetalvegetablewaxysweetfloral
MW
102.15
BP
155°C
MP
—
Sp.Gr.
0.92
Refractive n
—
Rotation
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Appearance

Colorless liquid.

Solubility

Almost insoluble in water, soluble in alcohol, propylene glycol and oils.

Odor

Dry-green, petal-like and vegetable-like odor with waxy-sweet undertones. The vegetable notes resemble those of cucumber and radish, yet without the sharpness of the latter. To some observers, it also appears floral.

Flavor

Semi-sweet, fresh-vegetable-green taste in dilutions below 2 ppm.

Uses in perfumery

This ester finds some use in perfumery as part of various topnote complexes. It blends very well with galbanum and with many herbaceous oils. Styrax is a good fixative, and supporting fixation and blending can be achieved with cinnamates. The ester could constitute the main part of the green theme in hyacinth when suitably incorporated.

Uses in flavor

In flavors, it forms an excellent combination with nonadienal and nonadienol in cucumber compositions and other vegetable, juicy-green flavor types. It is furthermore a generally refreshing modifier for the higher esters of the series.

Production

Produced from cis-3-hexenol and formic acid, e.g. in presence of acetic anhydride in cold formylation.

Identity
Aliases · 1
beta-gamma-Hexenyl methanoate
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).