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LINALYL BENZOATE

CAS
—
EC
—
Material type
synthetic aroma chemical
Canonical source
arctander
Formulation

Usage guidance

Suggested min
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Suggested max
—
Cost
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Stock
—
Compatibility tags
citrus
How it behaves

Olfactory profile

Family
resinous
Note tendency
Base
Descriptors
floralfruitybalsamic

A soft, mildly sweet floral-balsamic ester with a gentle woody-fruity nuance reminiscent of ylang and light balsam. Quieter and more tenacious than linalool itself, it lends a rounded, slightly powdery smoothness to floral and oriental accords.AI · claude-opus-4-7

Intensity
4 / 10
Tenacity
7 / 10
Volatility
4 / 10
Members

The rest of this material

Composition, IFRA restriction figures, allergen concentrations and where this material is bought are part of Perfume Foundry’s curated library and need an account. Create one or sign in.

chemicals · No. 1808

Arctander monograph

Perfume and Flavor Chemicals, page 766.

tenacity · highG.R.A.S.FEMA 2638
balsamicfloralfruitysweet
MW
198.24
BP
263°C
MP
—
Sp.Gr.
0.99
Refractive n
—
Rotation
—
Appearance

Almost colorless oily liquid.

Solubility

Insoluble in water, soluble in alcohol and oils.

Odor

Balsamic-floral, Bergamot-fruity odor of good tenacity. The odor varies considerably according to the method of production of this ester. Above description is based upon the Roche-processed material, while older methods yield esters of far greater sweetness, less tenacity and more similarity to Linalyl acetate, often with side-notes of Methylbenzoate. Peculiar, deep-sweet, fruity or fruit-preserve-like odor, mainly of Plum-type.

Flavor

This ester finds some use in flavor compositions for imitation Peach, Plum, Blackcurrant and other berries, fruit complexes or Citrus flavors. The concentration in the finished product will normally be about 0.3 to 2 ppm.

Uses in perfumery

An interesting material for new variations of the conventional theme in Men’s fragrances. Particularly suitable for outdoor type odors, Bruyere, woody-green, mossy-green or green-citrusy types. Also used in Oriental fragrances, in heavy florals such as Gardenia, Tuberose, Stephanotis, etc.

Production

1) from Linalyl formate plus Methylanthranilate with Sodium Linalool. 2) by esterification of Dehydrolinalool with Benzoic acid e.g. under azeotropic conditions, followed by hydrogenation of the Dehydro-ester. 3) from Linalool acetophenone.

Identity
Aliases · 1
F.E.M.A. No. 2638
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).