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4-Methyl Cyclotetradecan-1-One

CAS
EC
Material type
synthetic aroma chemical
Canonical source
arctander
How it behaves

Olfactory profile

Family
Note tendency
Top
Descriptors
fruity
Intensity
Tenacity
Volatility
chemicals · No. 1933

Arctander monograph

Perfume and Flavor Chemicals, page 825.

BASEtenacity · moderatepower · weak
sweetmuskywoody
MW
224.39
BP
117°C
MP
Sp.Gr.
0.8
Refractive n
Rotation
Appearance

Colorless liquid

Solubility

2% soluble in water, soluble in alcohol, miscible with oils. Soluble in Propylene glycol and Glycerin.

Odor

Powerful and diffusive ethereal-fruity odor of poor tenacity.

Flavor

Sweet-fruity, ethereal flavor in dilutions below 20 ppm. At higher concentrations the flavor appears more pungent, chemical and sharp.

Uses in perfumery

This ketone finds a little use in perfume compositions as a masking agent in industrial fragrances, etc.

Uses in flavor

It is more frequently used in flavor compositions for imitation Peach, Orange, Banana, Pineapple, Pear, Rum, etc. and in fruit complexes. The normal concentration is about 5 to 8 ppm in the finished product. Lately, it has found use in the reconstitution of flavor in Orange juice.

Production

1) By oxidation of Methyl-iso-butylcarbinol. However, the latter is more often produced from the ketone which is a petro chemical, commercially available in volume. 2) from Mesityloxide by hydrogenation.

Identity
Aliases · 4
4-Methyl-2-pentanonefso-Butylmethylketoneiso-Hexanone-2tso-Propylacetone
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).