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METHYL-2-HEXENOATE

CAS
—
EC
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Material type
synthetic aroma chemical
Canonical source
arctander
Formulation

Usage guidance

Suggested min
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Suggested max
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Cost
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Stock
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Compatibility tags
fruityfresh-fruityapple-accordtop-note-lift
How it behaves

Olfactory profile

Family
green
Note tendency
Top
Descriptors
fruitygreensweetearthy

A green, fruity ester with a bright apple-pear character and a slightly sharp, unripe green edge. Reminiscent of freshly cut apple skin with a light, sweet-sour lift.AI · claude-opus-4-7

Intensity
6 / 10
Tenacity
3 / 10
Volatility
8 / 10
Members

The rest of this material

Composition, IFRA restriction figures, allergen concentrations and where this material is bought are part of Perfume Foundry’s curated library and need an account. Create one or sign in.

chemicals · No. 2053

Arctander monograph

Perfume and Flavor Chemicals, page 880.

tenacity · moderatepower · strongG.R.A.S.FEMA 2709
greenmustyearthysweetfruity
MW
142.2
BP
169°C
MP
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Sp.Gr.
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Refractive n
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Rotation
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Appearance

Colorless mobile liquid.

Solubility

Very slightly soluble in water, soluble in alcohol and oils.

Odor

Green-musty, earthy-sweet and fruity odor of moderate to poor tenacity.

Flavor

This ester is used in flavor compositions for the type of fruit flavor demanding a rather sharp and green fruity topnote, such as Pineapple, Strawberry, etc. and in various fruit complexes.

Uses in flavor

It is quite powerful, and the concentration used is normally equivalent to only 0.05 to 0.1 ppm in the finished product.

Production

Produced by direct esterification. The acid is obtained from reacting Butyraldehyde with Malonic acid. A certain amount of 3-Hexenoic acid is formed, but it can be rearranged to the 2-Hexenoic acid.

Identity
Aliases · 4
Methyl-alpha-bera-hexenoateMethyl-beta-propylacrylateMethyl hexadienoateMethyl sorbate
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).