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Benzyl Cinnamate

RESTRICTION
CAS
103-41-3
EC
Material type
other
Canonical source
document derived
chemicals · No. 299

Arctander monograph

Perfume and Flavor Chemicals, page 134.

tenacity · highG.R.A.S.FEMA 2142
sweetbalsamicfloral
MW
162.19
BP
MP
35°C
Sp.Gr.
Refractive n
Rotation
Appearance

White crystals, granular or powder.

Solubility

Insoluble in water, propylene glycol and glycerin. Soluble in alcohol and oils.

Odor

Mild, sweet-balsamic and somewhat floral odor of great tenacity.

Uses in perfumery

Used quite frequently in perfumery, mainly as a fixative, and particularly in perfumes for talcum powders. It blends well with floral bases, spicy fragrances and ambre types.

Uses in flavor

Used in flavor compositions for imitation apricot, cherry, chocolate, honey, peach, pineapple, liquor, raspberry, rum, prune, etc.

Production

Produced from sodium cinnamate and benzyl chloride (with or without catalyst). Other methods start from benzyl acetate and benzaldehyde, using a Claisen type condensation, etc.

Document-derived

IFRA restrictions

CategoryKindMax %NotesSource
Category 1Max %0.36%
DOC
Category 2Max %0.11%
DOC
Category 3Max %1.2%
DOC
Category 4Max %2%
DOC
Category 5AMax %0.51%
DOC
Category 5BMax %0.51%
DOC
Category 5CMax %0.51%
DOC
Category 5DMax %0.17%
DOC
Category 6Max %1.2%
DOC
Category 7AMax %2.4%
DOC
Category 7BMax %2.4%
DOC
Category 8Max %0.17%
DOC
Category 9Max %3.9%
DOC
Category 10AMax %3.9%
DOC
Category 10BMax %14%
DOC
Category 11AMax %0.17%
DOC
Category 11BMax %0.17%
DOC
Category 12No restrictionNo Restriction
DOC

Compliance-support only. Values resolved from the current IFRA corpus; each row cites the document excerpt it came from. Not a substitute for a qualified safety assessor.

IFRA Annex I

Found naturally in

Natural complex substances (NCSs) in which this material typically occurs.

NCSBotanicalTypical %
Peru BalsamMyroxylon balsamum (L.) Harms var. pereirae (Royle) Harms15.2%
Tolu, balsam, extractMyroxylon balsamum (L.) Harms.2.6%
Styrax OilLiquidambar styraciflua L.1%
Benzoin extract, SumatraStyrax benzoin Dryand.0.8%
Benzoin extract, SiamStyrax tonkinensis Craib0.8%
Identity
Aliases · 9
103-41-3Benzyl cinnamate2-Propenoic acid, 3-phenyl-phenylmethyl esterBenzyl 3-phenylpropenoateBenzyl-beraphenylacrylateBenzyl γ-phenylacrylateCinnameinCinnamic acid, benzyl esterPhenylmethyl 3-phenyl-2-propenoate
Compliance note. Restriction data is sourced directly from IFRA publications and preserved with its document excerpt. Perfume Foundry is a compliance-support tool — not a substitute for a qualified safety assessor (CPSR / PIF).